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Polymer chains : structure, physical properties, and industrial uses / editors, R�egine Penzkofer and Yasue Wu.

Contributor(s): Material type: TextTextSeries: Chemical engineering methods and technology | Polymer science and technologyPublisher: Hauppauge, N.Y. : Nova Science Publishers, c2012Description: 1 online resourceContent type:
  • text
Media type:
  • computer
Carrier type:
  • online resource
ISBN:
  • 9781621004592
  • 1621004597
Subject(s): Genre/Form: Additional physical formats: Print version:: Polymer chainsDDC classification:
  • 547/.28 23
LOC classification:
  • TP156.P6
Other classification:
  • UV 2200
Online resources:
Contents:
POLYMER CHAINS: STRUCTURE, PHYSICAL PROPERTIES AND INDUSTRIAL USES; POLYMER CHAINS: STRUCTURE, PHYSICAL PROPERTIES AND INDUSTRIAL USES; Library of Congress Cataloging-in-Publication Data; CONTENTS; PREFACE; Chapter 1: ON THE FLEXIBILITY OF POLYHETEROARYLENES AND THE EFFECT ON SEVERAL PHYSICAL PROPERTIES OF THESE POLYMERS; ABSTRACT; INTRODUCTION; I. CONFORMATIONAL PARAMETERS WITH FREE ROTATION; II. ASSEMENT OF CONFORMATIONAL PARAMETERS FROM HYDRODYNAMIC DATA; III. EFFECT OF SIDE GROUPS; IV. RIGID-CHAIN POLYMERS; V. CALCULATION OF THE FREE, OCCUPIED AND ASSUME VOLUMES.
VI. THE EFFECT CONFORMATIONAL RIGIDITY ON SEVERALPHYSICAL PROPERTIES OF THESE POLYMERS1. Glass Transition Temperature; 2. Coefficient of Friction; 3. Elastic Properties; 4. The Relationship between the Fire Resistance and the Kuhn Segment; 5. Conformational Rigidity and Transport Properties; 6. Conformational Rigidity and Dielectric Permittivity; 6. Conformational Rigidity and Electrets Properties; CONCLUSION; REFERENCES; Chapter 2: ALIPHATIC POLYESTER-BASED NANOCOMPOSITES; 1. OVERVIEW.
2. EFFECT OF HYDROGEN BONDING ON THE CRYSTALLIZATION BEHAVIOR OF POLY(3-HYDROXYBUTYRATE-CO-3-HYDROXYHEXANOATE)/SILICA HYBRID COMPOSITES2-1. Introduction; 2-2. Experimental; 2-2-1. Materials and Sample Preparation; 2-2-2. Measurements; 2-3. Results and Discussion; 2-3-1. Intermolecular Hydrogen Bonding; 2-3-2. Quantitative Analysis of the Fraction of the Intermolecular Hydrogen Bond; 2-3-3. Non-Isothermal Crystallization Behavior; 2-3-4. Isothermal Crystallization Kinetics; 2-4. Summary; References.
3. IN SITU POLYMERIZED POLY(BUTYLENE SUCCINATE)/SILICA NANOCOMPOSITES: PHYSICAL PROPERTIES AND BIODEGRADATION3-1. Introduction; 3-2. Experimental; 3-2-1. Materials and Polymerization; 3-2-2. Solid-State 29Si NMR Spectroscopy and Polymer Characterization; 3-2-3. Melt Rheological Analysis; 3-2-4. Stress-Strain Measurements; 3-2-5. Wide Angle X-Ray Diffraction (WAXD) and Transmission Electron Microscopy (TEM); 3-2-6. Preparation of the Mature Compost; 3-3. Evaluation of Biodegradability in the Mature Compost; 3-4. Results and Discussion; 3-5. Summary; References.
4. EFFECT OF ISOCYANATE-MODIFIED FUMED SILICA ON THE PROPERTIES OF POLY(BUTYLENE SUCCINATE) NANOCOMPOSITES4-1. Introduction; 4-2. Experimental; 4-2-1. Materials; 4-2-2. Modification of the Silica Particles; 4-2-3. Preparation of PBS Nanocomposites; 4-2-4. Separation of Silica Powder from the Nanocomposites; 4-2-5. Characterization of the Modified Silica Particles and PBS Nanocomposites; 4-3. Results and Discussion; 4-3-1. Characterization of the Modified Silica Particles; 4-4. Characterization of the PBS Nanocomposites; 4-4-1. Reaction Time and Intrinsic Viscosity; 4-4-2. FTIR Spectra.
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Includes bibliographical references and index.

Description based on print version record.

English.

POLYMER CHAINS: STRUCTURE, PHYSICAL PROPERTIES AND INDUSTRIAL USES; POLYMER CHAINS: STRUCTURE, PHYSICAL PROPERTIES AND INDUSTRIAL USES; Library of Congress Cataloging-in-Publication Data; CONTENTS; PREFACE; Chapter 1: ON THE FLEXIBILITY OF POLYHETEROARYLENES AND THE EFFECT ON SEVERAL PHYSICAL PROPERTIES OF THESE POLYMERS; ABSTRACT; INTRODUCTION; I. CONFORMATIONAL PARAMETERS WITH FREE ROTATION; II. ASSEMENT OF CONFORMATIONAL PARAMETERS FROM HYDRODYNAMIC DATA; III. EFFECT OF SIDE GROUPS; IV. RIGID-CHAIN POLYMERS; V. CALCULATION OF THE FREE, OCCUPIED AND ASSUME VOLUMES.

VI. THE EFFECT CONFORMATIONAL RIGIDITY ON SEVERALPHYSICAL PROPERTIES OF THESE POLYMERS1. Glass Transition Temperature; 2. Coefficient of Friction; 3. Elastic Properties; 4. The Relationship between the Fire Resistance and the Kuhn Segment; 5. Conformational Rigidity and Transport Properties; 6. Conformational Rigidity and Dielectric Permittivity; 6. Conformational Rigidity and Electrets Properties; CONCLUSION; REFERENCES; Chapter 2: ALIPHATIC POLYESTER-BASED NANOCOMPOSITES; 1. OVERVIEW.

2. EFFECT OF HYDROGEN BONDING ON THE CRYSTALLIZATION BEHAVIOR OF POLY(3-HYDROXYBUTYRATE-CO-3-HYDROXYHEXANOATE)/SILICA HYBRID COMPOSITES2-1. Introduction; 2-2. Experimental; 2-2-1. Materials and Sample Preparation; 2-2-2. Measurements; 2-3. Results and Discussion; 2-3-1. Intermolecular Hydrogen Bonding; 2-3-2. Quantitative Analysis of the Fraction of the Intermolecular Hydrogen Bond; 2-3-3. Non-Isothermal Crystallization Behavior; 2-3-4. Isothermal Crystallization Kinetics; 2-4. Summary; References.

3. IN SITU POLYMERIZED POLY(BUTYLENE SUCCINATE)/SILICA NANOCOMPOSITES: PHYSICAL PROPERTIES AND BIODEGRADATION3-1. Introduction; 3-2. Experimental; 3-2-1. Materials and Polymerization; 3-2-2. Solid-State 29Si NMR Spectroscopy and Polymer Characterization; 3-2-3. Melt Rheological Analysis; 3-2-4. Stress-Strain Measurements; 3-2-5. Wide Angle X-Ray Diffraction (WAXD) and Transmission Electron Microscopy (TEM); 3-2-6. Preparation of the Mature Compost; 3-3. Evaluation of Biodegradability in the Mature Compost; 3-4. Results and Discussion; 3-5. Summary; References.

4. EFFECT OF ISOCYANATE-MODIFIED FUMED SILICA ON THE PROPERTIES OF POLY(BUTYLENE SUCCINATE) NANOCOMPOSITES4-1. Introduction; 4-2. Experimental; 4-2-1. Materials; 4-2-2. Modification of the Silica Particles; 4-2-3. Preparation of PBS Nanocomposites; 4-2-4. Separation of Silica Powder from the Nanocomposites; 4-2-5. Characterization of the Modified Silica Particles and PBS Nanocomposites; 4-3. Results and Discussion; 4-3-1. Characterization of the Modified Silica Particles; 4-4. Characterization of the PBS Nanocomposites; 4-4-1. Reaction Time and Intrinsic Viscosity; 4-4-2. FTIR Spectra.

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